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Journal of Advanced Marine Engineering and Technology - Vol. 45 , No. 3
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[ Original Paper ]
Journal of Advanced Marine Engineering and Technology - Vol. 45, No. 3, pp. 88-93
Abbreviation: JAMET
ISSN: 2234-7925 (Print) 2765-4796 (Online)
Print publication date 30 Jun 2021
Received 19 Mar 2021 Revised 14 Apr 2021 Accepted 12 May 2021
DOI: https://doi.org/10.5916/jamet.2021.45.3.88

Effect of analyzer scan time on the oxygen storage capacity performance in Pd-based TWCs
Daekun Kim†

Correspondence to : †Researcher, Department of Mechanical Engineering, University of Tennessee, 1512 Middle Drive, Knoxville, TN, 37996, USA, E-mail: kkun@vols.utk.edu, Tel: +01-865-347-7226


Copyright © The Korean Society of Marine Engineering
This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0), which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract

Oxygen storage materials play an important role in increasing the performance of three-way catalysts. However, high operating temperatures and lubricant additives result in a reduction in the oxygen storage capacity (OSC), thus shortening the life of the catalyst. Therefore, it is important to measure and investigate OSCs using an appropriate protocol to evaluate catalyst’s performance and deactivation. In this study, the effect of analyzer scan time on the OSC performance of a commercial monolith three-way catalyst containing oxygen storage materials such as cerium-zirconium mixed oxide was investigated in a bench-flow reactor, and an appropriate scan time was suggested based on these results. This study also investigated OSC as a function of inlet gas temperatures between 300 and 550 °C. The results suggest that the OSC experiment should be performed using a scan time of at least 4.0 s, while reliable dynamic OSC results cannot be obtained if the analyzer scan time is longer than 4 s. Therefore, a study is required in order to determine the optimal OSC scan time to ensure accuracy, while also retaining an acceptable level of resolution. It was also confirmed that the OSC increases with increasing inlet gas temperature up to a temperature of 450 °C, but no longer increases above 450 °C.

Keywords: Pd-based three-way catalyst, Oxygen storage capacity, Ceria-zirconia mixed oxide, Bench-flow reactor
1. Introduction

Three-way catalysts (TWCs) are widely used to effectively control the emission of nitrogen oxides (NOx), carbon monoxide (CO), and hydrocarbons (HCs), which are harmful substances contained in the exhaust gases of gasoline engines, by converting them into nitrogen (N2), carbon dioxide (CO2), and water vapor (H2O) [1]. The three-way catalytic conversion efficiencies of NO, CO, and unburnt hydrocarbons (UHCs) exhibited the highest performance at air-fuel (A/F) ratios close to the stoichiometric point (14.7: 1). However, under excessive air supply conditions (fuel-lean conditions above A/F = 14.7, or λ = 1), the reaction of NO reductants with excessive air causes a shortage of the NO reducing agent, which significantly reduces NO conversion. Therefore, gasoline engines are designed to operate in narrow bands or windows close to the stoichiometric ratio, and an oxygen (O2) sensor (or lambda sensor) must be installed downstream of the catalytic converter to determine the optimal A/F ratio for the conversion of harmful gases. However, engine operating conditions which change frequently during operation can induce A/F ratio oscillations owing to the feedback from the O2 sensor to the engine control unit, making it difficult to maintain stoichiometric points. For this reason, cerium oxide (CeO2), a well-known oxygen storage material, is added to the washcoat to improve the conversion efficiency of CO, HC, and NOx by storing and releasing O2 according to Ce4+/Ce3+ redox reactions [2][3]. However, pure CeO2 generally exhibits poor thermal stability and weak metal-CeO2 interactions [4]-[6]. To enhance the thermal stability of TWCs, several other oxides such as zirconia (ZrO2), silicon dioxide (SiO2), barium oxide (BaO), and lanthanum oxide (La2O3) have been added to the catalyst in appropriate quantities [7]-[17].

In accordance with the recently revised United States Environmental Protection Agency standard Tier 3 regulations, catalyst lifespan regulations have been strengthened from 12,000 miles to 150,000 miles. To meet this requirement, ongoing efforts have been made to determine the causes of catalyst deactivation, thereby extending the catalyst life. One general cause of catalyst deactivation is the degradation of the oxygen storage capacity (OSC) due to high temperature exposure, which may occur as a result of the agglomeration of the oxygen storage material, or a reduction in catalytic activity owing to the contact between the sintered precious metal and oxide support [18]-[20]. In addition, deactivation of TWC performance has been attributed to the formation of cerium orthophosphate (CePO4) and zinc pyrophosphate (Zn2P2O7) compounds within the washcoat of the catalyst caused by lubricant additives (poisoning) [21]-[26].

The OSC experiment is one of the several studies that has investigated the performance and deactivation of TWC by probing the performance of CeO2, an oxygen storage material and a key component of the TWC washcoat. However, protocols for obtaining accurate results from OSC experiments performed in a bench flow reactor (BFR) using a Fourier transform infrared (FTIR) analyzer and explanations of the effects of these experimental procedures on the OSC results are lacking. Herein, this study presents an experimental method for dynamic OSC measurement in a BFR, while the effect of the scan time of FTIR on OSC results was investigated using a Pd-based TWC.

2. Experimental Apparatus and Procedure
2.1 Bench flow reactor system

Figure 1 shows a schematic of the BFR system. The BFR mainly consists of mass flow controllers (MFCs), a quartz tube reactor enclosed in a temperature-programmable furnace, and an FTIR spectrometer. A more detailed explanation of the BFR is provided in a previous study [26][27]. For this experiment, a three-way switching valve was installed in the BFR to alternate the flow between the lean and rich banks. Each gas that passed through the MFCs was supplied from an individual gas cylinder. The CO and CO2 concentrations at the inlet and exit were measured with an MIDAC-M2000 FTIR spectrometer using the software Essential FTIR.


Figure 1: 
Schematic diagram of the bench flow reactor (BFR) system. More details can be found in [26][27].

2.2. Three-way catalyst

The TWCs used for OSC measurements in the present study were obtained from a 2009 MY Jeep Liberty V6 from a local dealership. Inductively coupled plasma mass spectrometry (ICPMS), electron probe microanalysis (EPMA), and X-ray diffraction (XRD) analyses were used to identify cerium (Ce), the oxygen storage material in the catalyst, as follows. ICP-MS analysis confirmed that this Pd-based TWC was primarily composed of Mg, Al, Ba, Ce, and Zr. In addition, precious metals, palladium (Pd) and rhodium (Rh), were detected in a weight ratio of 8:1 with respect to the bulk material. In a previous paper [26], the peak of mixed oxides (CexZr1-xO2) was clearly detected in the XRD pattern at 2θ = 29.2°.

Figure 2 shows the EPMA element map of Ce for the Pd-based TWC sample. As shown in Figure 2, the results obtained from the EPMA elemental map confirm the presence of Ce in the washcoat of the TWC. Although Ce could not be detected quantitatively, it was confirmed that the OSC material of the Pd-based TWC was Ce-Zr mixed oxides.


Figure 2: 
EPMA element map of cerium (Ce) in the TWC sample

2.3 Oxygen storage capacity evaluation protocol

Although FTIR spectroscopy cannot measure homonuclear diatomic molecules such as N2 and O2, it is a suitable analyzer for OSC investigations as multiple gaseous species, such as CO and CO2, can be measured simultaneously and in real time at high temperatures. The O2 storage reaction under lean conditions and OSC reduction reaction under rich conditions are given by the following reactions [28]:

Ce2O3+0.5O2↔2CeO2(1) 
CO+2CeO2↔Ce2O3+CO2(2) 

Figure 3 shows the CO and CO2 data plotted as a function of time to quantify the OSC. During the lean cycle, O2 is stored in the cerium (Equation 1), and the stored O2 is subsequently released and reacts with CO during the rich cycle to produce CO2 (Equation 2). The OSC was calculated as a normalized value as a function of the volume for the TWC (g-O2/L-catalyst) through an integration of the quantity of CO2 produced under rich conditions.


Figure 3: 
Example of CO and CO2 curves for OSC measurement

Prior to a performance evaluation of the BFR, the fresh TWC sample was subjected to a degreening process in order to enhance its stability. The gas composition during the degreening process consisted of 10% CO2, 10% H2O, and 80% N2 supplied at a gas hourly space velocity (GHSV) of 60,000 h-1 and a gas inlet temperature of 700°C for four h.

An OSC experiment was carried out for the fresh TWC sample under a slow cycle consisting of 120 s lean and 120 s rich for a total of four cycles (total duration of 720 s) in a temperature range between 300 and 550°C measured in 50°C increments at a GSHV of 60,000 h-1. The feed gas compositions during the lean and rich cycles are listed in Table 1. N2 gas was introduced at each temperature for approximately 10 min prior to the OSC measurement to remove any residual CO from the precious metal sites still present from the last cycle at the previous temperature. To investigate the effect of the FTIR scan time on the OSC results, the OSC experiment on the fresh sample was performed at two different FTIR scan times (1.5 s and 9.0 s) by varying the spectral resolution.

Table 1: 
Gas compositions for OSC
Mode Time Gas Composition
Lean 120 s 0.73% O2, balance N2
Rich 120 s 0.50% CO, balance N2

3. Results and Discussion

Figures 4 (a) and (b) show the results of the oxygen storage process during the lean/rich cycle at an inlet gas temperature of 350 °C using FTIR scan times of 9.0 s (shown in 4a) and 1.5 s (shown in 4b). As described in section 2.3, O2 is stored in a mixed oxide on Pd sites during the lean cycle and subsequently released during the rich cycle. The O2 released during this process reacts with CO during the rich cycle to produce CO2, as shown in Figure 4.


Figure 4: 
Full scale OSC with resulting CO and CO2 concentration for the fresh sample obtained from FTIR scan times of (a) 9.0 s and (b) 1.5 s at an inlet gas temperature of 350°C

Since the OSC is calculated as an average value using the CO2 produced under rich conditions, it is necessary to ensure that the amount of CO2 produced is similar in each cycle for obtaining accurate OSC measurements. As shown in Figure 4 (a), when a scan time of 9.0 s was used, the CO concentration remained constant during the rich cycle, while the concentration of CO2 produced varied with each cycle. In contrast, when a scan time of 1.5 s was used, the CO concentration remained constant throughout all rich cycles, while the amount of CO2 produced also remained constant, as shown in Figure 4 (b). These results indicate that OSC measurements should be performed before reaching the maximum CO2 production and that a scan time of 9.0 s is insufficient. In essence, OSC measurements obtained from a scan time of 9.0 s yield inaccurate results exhibiting large deviations. A detailed explanation is provided below and is illustrated in Figure 5. Also noteworthy is the point at which the CO2 concentration increased as the local environment transitioned from rich to lean conditions. For example, between 240 s and 250 s, the CO2 concentration increased to a local maximum and then rapidly decreased. This occurred as a result of the CO being retained in the line during the switch from rich to lean conditions being fed to the catalyst along with the supplied O2 using the 3-way valve. Therefore, this period of overlap should be excluded from the OSC calculations.


Figure 5: 
An expanded portion of Figure 4 (b) between 120 s and 140 s

Based on the CO2 curve generated in Figure 4, OSCs for 1.5 and 9.0 s scan times from each cycle were obtained and are listed in Table 2, including the standard deviation (σ). As expected, the OSC deviation obtained from a 1.5 s scan time is significantly lower than that with a 9.0 s scan time.

Table 2: 
OSC results of the fresh sample at two different FTIR scan times
Scan time OSC [in g-O2/L-catalyst]
1st 2nd 3rd 4th Average ± σ
1.5 s 0.728 0.715 0.709 0.713 0.716 ± 0.008
9.0 s 0.822 0.716 0.536 0.925 0.750 ± 0.166

The magnified section of Figure 4 at a time between 120 and 140 s is shown in Figure 5 and indicates a suitable FTIR scan time for OSC measurements. A significant increase in the CO2 concentration was observed owing to the reaction of the stored O2 with the CO introduced between 120.0 s and 124.5 s, with the CO2 concentration decreasing after 124.5 s. Therefore, at an inlet gas temperature of 350 °C, it can be determined that the OSC should be obtained in less than 4 s. This is the amount of time required to perform the FTIR scan prior to reaching the point of maximum CO2 formation.

Figure 6 shows a comparison of the OSC results obtained from two different FTIR scan times in the temperature range between 300–550°C measured in 50°C increments. As Figure 6 shows, the inlet gas temperature has a significant effect on the OSC. It has been observed in previous studies that OSC performance is strongly dependent on temperature [18][29]. The OSC results obtained from the 1.5 s and 9.0 s FTIR scan times show that the higher the inlet gas temperature, the higher the OSC. However, when the inlet gas temperature exceeded 450°C, the OSC no longer continued to increase for either FTIR scan time. In a previous study [30], it was observed that the OSC no longer increases at temperatures above 450°C owing to oxygen storage limitations as a result of bulk diffusion. However, the OSC obtained from a 9.0 s FTIR scan time exhibited a larger standard deviation than the OSC obtained from a 1.5 s FTIR scan time. At a 1.5 s FTIR scan time, the OSC results obtained were repeatable across all temperature ranges.


Figure 6: 
OSC comparison with different FTIR scan times at temperatures between 300 and 550°C

4. Conclusions and Recommendations

In the present investigation, the effect of FTIR scan times on the OSC results of Pd-based TWCs were investigated. OSC materials such as Ce and Zr present in TWCs were identified qualitatively through surface characterization techniques such as XRD, EPMA, and ICP-MS analysis. In addition, the OSC performance was evaluated over feed gas temperatures ranging between 300 and 550°C measured in 50°C increments. This study revealed the following points regarding the effect of the FTIR scan time and inlet gas temperature on the OSC results.

  • 1) With a 9.0 s FTIR scan time, the OSC results are unreliable due to the significant variations in CO2 production during each rich cycle period.
  • 2) Measuring the OSC with a short FTIR scan time (1.5 s) obtained reliable OSC results exhibiting similar CO2 production curves for each rich cycle period.
  • 3) These results indicate that in order to reduce the experimental error of the OSC results, it is necessary to determine a suitable FTIR scan time that can be used to evaluate the OSC performance of the TWC in the BFR using an FTIR analyzer. As far as the FTIR performance permits, it is advisable to measure the OSC using rapid scan times, but if not, it is recommended to measure the OSC using an FTIR scan time of at least 4 s to obtain reliable results. (See Figure 5).
  • 4) When calculating the OSC, the CO2 produced in the process of switching the 3-way valve from rich to lean should be excluded.
  • 5) For the Pd-based TWC used in this study, the OSC increased with increasing temperature up to 450°C. Above 450°C, no further increase in the OSC occurred.

The most significant finding in this investigation was that shorter FTIR scan times yield more reliable OSC results. However, short FTIR scan times can only be obtained by reducing the FTIR resolution. Therefore, before performing OSC experiments using FTIR, a further investigation should be conducted to determine the optimal scan time to obtain accurate dynamic OSC results.

Author Contributions

Conceptualization, D. K. Kim; Methodology, D. K. Kim; Validation, D. K. Kim; Experiments, D. K. Kim; Resources, D. K. Kim; Data Curation, D. K. Kim; Results Analysis, D. K. Kim; Writing-Original Draft Preparation, D. K. Kim; Writing-Review & Editing, D. K. Kim; Visualization, D. K. Kim; Supervision, D. K. Kim.

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